Catalysts, Vol. 13, Pages 664: Supported Ionic Liquid Catalysts for the Oxidation of S- and N-Containing Compounds—The Effect of Bronsted Sites and Heteropolyacid Concentration

Catalysts, Vol. 13, Pages 664: Supported Ionic Liquid Catalysts for the Oxidation of S- and N-Containing Compounds—The Effect of Bronsted Sites and Heteropolyacid Concentration

Catalysts doi: 10.3390/catal13040664

Authors: Vladislav Gorbunov Aleksey Buryak Kirill Oskolok Andrey G. Popov Irina Tarkhanova

In this article, a series of effective catalysts based on betaine and sulfuric or phosphomolybdic acids was obtained. These compositions were characterized by various physicochemical methods and tested in the oxidation of sulfur- and nitrogenous-containing compounds by H2O2. An increase in the amount of heteropolyacid (HPA) leads to a non-linear change in acidity, and the degree of removal of sulfur-containing compounds correlates with the concentration of Bronsted acid sites on the surface. On the contrary, the degree of pyridine removal is determined primarily by the content of heteropolyacids in the catalyst.