Crystals, Vol. 13, Pages 879: Nanostructured Mn–Ni Powders Produced by High-Energy Ball-Milling for Water Decontamination from RB5 Dye

Crystals, Vol. 13, Pages 879: Nanostructured Mn–Ni Powders Produced by High-Energy Ball-Milling for Water Decontamination from RB5 Dye

Crystals doi: 10.3390/cryst13060879

Authors: Wael Ben Mbarek Mohammed Al Harbi Bechir Hammami Mohamed Khitouni Luisa Escoda Joan-Josep Suñol

In this study, the degradation efficiency of Mn-20at%Ni and Mn-30at%Ni particle powders made by melt-spinning and high-energy ball-milling techniques is investigated in relation to the degradation of the azo dye Reactive Black 5. SEM, EDS, and XRD were used to analyze the powders’ morphology, surface elemental composition, and phase structure. An ultraviolet-visible absorption spectrophotometer was used to measure the ball-milled powder’s capacity to degrade, and the collected powders were examined using the FTIR spectroscopy method to identify the substituents in the extract. The impact of MnNi alloy on the azo dye Reactive Black 5′s degradation and its effectiveness as a decolorizing agent were examined as functions of different parameters such as chemical composition, specific surface, and temperature. In comparison to the Mn-30at%Ni alloy, the powdered Mn-20at%Ni particles show better degrading efficiency and a faster rate of reaction. This remarkable efficiency is explained by the configuration of the valence electrons, which promotes more responding sites in the d-band when the Ni content is reduced. Therefore, increased electron transport and a hastened decolorization process are achieved by reducing the Ni concentration of RB5 solution with Mn80 particle powder. Additionally, this difference in their decolorization efficiency is explained by the fact that Mn-20at%Ni has the highest specific surface area of 0.45 m2 g−1. As the main result, the functional uses of nanostructured metallic powder particles as organic pollution decolorizers in the textile industry are greatly expanded by our study.