Nanomaterials, Vol. 14, Pages 2025: Bimetallic Mesoporous MCM-41 Nanoparticles with Ta/(Ti, V, Co, Nb) with Catalytic and Photocatalytic Properties

Nanomaterials, Vol. 14, Pages 2025: Bimetallic Mesoporous MCM-41 Nanoparticles with Ta/(Ti, V, Co, Nb) with Catalytic and Photocatalytic Properties

Nanomaterials doi: 10.3390/nano14242025

Authors: Viorica Parvulescu Gabriela Petcu Nicoleta G. Apostol Irina Atkinson Simona Petrescu Adriana Baran Daniela C. Culita Ramona Ene Bogdan Trica Elena M. Anghel

Bimetallic (Ta/Ti, V, Co, Nb) mesoporous MCM-41 nanoparticles were obtained by direct synthesis and hydrothermal treatment. The obtained mesoporous materials were characterized by XRD, XRF, N2 adsorption/desorption, SEM, TEM, XPS, Raman, UV-Vis, and PL spectroscopy. A more significant effect was observed on the mesoporous structure, typically for MCM-41, and on optic properties if the second metal (Ti, Co) did not belong to the same Vb group with Ta as V and Nb. The XPS showed for the TaTi-MCM-41 sample that framework titanium is the major component. The new nanoparticles obtained were used as catalysts for oxidation with hydrogen peroxide of olefinic compounds (1,4 cyclohexadiene, cyclohexene, styrene) and photodegradation of organic pollutants (phenol, methyl orange) from water. The results showed improvementsin activity and selectivity in oxidation reactions by the addition of the second metal to the Ta-MCM-41 catalyst. The slow addition of H2O2 was also beneficial for the selectivity of epoxide products and the stability of the catalysts. The band gap energy values decreased in the presence of the second metal, and the band edge diagram evidenced positive potential for all the conduction bands of the bimetallic samples. The highestlevels of photocatalytic degradation were obtained for the samples with TaTi and TaV.