Sustainability, Vol. 15, Pages 5419: Structural Characterization of Geopolymers with the Addition of Eggshell Ash

Sustainability, Vol. 15, Pages 5419: Structural Characterization of Geopolymers with the Addition of Eggshell Ash

Sustainability doi: 10.3390/su15065419

Authors: Marija Ivanović Sanja Knežević Miljana M. Mirković Ljiljana Kljajević Dušan Bučevac Vladimir B. Pavlović Miloš Nenadović

It is well known that geopolymers are a new group of binder materials of alumosilicate origin. Geopolymers are made by the reaction of precursor aluminosilicate materials with alkaline activator solutions. The current research relates to a low-cost and eco-friendly procedure, suitable of being implemented in two easy steps. The first step is the production of a solid phase based on fly ash (Obrenovac, Serbia) and eggshell ash as waste materials rich in calcium. The second step is alkali activating the solid phase using an alkaline activator (a mixture of NaOH and Na2SiO3) and procedures in proper laboratory conditions. Four samples with different eggshell ash content were synthesized. The concentration of used NaOH was 12 mol dm−3. The structural properties of all investigated samples were analyzed by XRD (X-ray diffraction), DRIFT (diffuse reflectance infrared Fourier transform), SEM (scanning electron microscopy) and UV/Vis spectroscopy analysis. XRD determined the amorphous halo with the presence of quartz as the crystal phase in all of the investigated samples. These results were confirmed by DRIFT analysis. The morphology of the samples was determined by SEM analysis. UV/Vis showed that the material could be a potential adsorbent.